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71.
《化学:亚洲杂志》2017,12(4):459-464
A method that allows hindered ortho ‐substituted aryl iodides to be efficiently coupled to phenylboronic acid using a gold‐catalyzed C−C bond formation is presented. The use of a molecularly‐defined dinuclear gold chloride catalytic precursor that is stabilized by a new tetradentate (N ,N′ )‐diamino‐(P,P′ )‐diphosphino ferrocene hybrid ligand in a Suzuki‐type reaction is described for the first time. Electron‐rich isopropyl groups on phosphorus were found essential for a superior activity, while the performances of a set of analogous gold dinuclear complexes that were fully characterized by multinuclear NMR spectroscopy and XRD analysis, were investigated. Therefore, arylation of para and ortho ‐substituted iodoarenes bearing electron‐rich, electron‐poor functional groups, and even hindered polycyclic aromatic compounds is described. 相似文献
72.
Dang Van Hieu 《Mathematical Methods in the Applied Sciences》2017,40(11):4065-4079
Based on the extended extragradient‐like method and the linesearch technique, we propose three projection methods for finding a common solution of a finite family of equilibrium problems. The linesearch used in the proposed algorithms has allowed to reduce some conditions imposed on equilibrium bifunctions. The strongly convergent theorems are established without the Lipschitz‐type condition of bifunctions. The paper also helps in the design and analysis of practical algorithms and gives us a generalization of some previously known problems. Copyright © 2017 John Wiley & Sons, Ltd. 相似文献
73.
Zoi G. Lada Amaia Soto Beobide Georgios N. Mathioudakis George A. Voyiatzis 《Molecules (Basel, Switzerland)》2021,26(1)
Polymeric composites constitute an appealing class of materials with applications in various fields. Spin crossover (SCO) coordination complexes are switchable materials with potential use in data storage and sensors. Their incorporation into polymers can be considered an effective method for their wider practical application. In this study, Fe(II) SCO/polylactic acid hybrid polymeric composites have been prepared by film casting. The mononuclear coordination complex [Fe{N(CN)2}2(abpt)2] was incorporated into polylactic acid. The morphological, structural and thermoanalytical characterization of the composite films were performed via scanning electron microscopy (SEM), attenuated total reflectance (ATR/FTIR), Raman spectroscopy and differential scanning calorimetry (DSC). In addition, the migration release study (MRS) of the SCO compound from the polymeric matrix into the food simulant 50% v/v water/ethanol solution was also examined via UV/Vis absorption. Of particular interest was the investigation of the SCO behavior of the coordination complex after its incorporation into the polymer matrix; it was accomplished by temperature-dependent micro-Raman spectroscopy. The described attempt could be considered a preparatory step toward the development of SCO-based temperature sensors integrated into food packaging materials. 相似文献
74.
Kiho Lee Ji-Yoon Lee Kyeong Lee Cho-Rock Jung Min-Ju Kim Jung-Ah Kim Dong-Gu Yoo Eun-Jin Shin Soo-Jin Oh 《Molecules (Basel, Switzerland)》2021,26(7)
A novel HIF (hypoxia-inducible factor)-1α inhibitor, the (aryloxyacetylamino)benzoic acid derivative LW6, is an anticancer agent that inhibits the accumulation of HIF-1α. The aim of this study was to characterize and determine the structures of the metabolites of LW6 in ICR mice. Metabolite identification was performed using a predictive multiple reaction monitoring-information dependent acquisition-enhanced product ion (pMRM-IDA-EPI) method in negative ion mode on a hybrid triple quadrupole-linear ion trap mass spectrometer (QTRAP). A total of 12 metabolites were characterized based on their MS/MS spectra, and the retention times were compared with those of the parent compound. The metabolites were divided into five structural classes based on biotransformation reactions: amide hydrolysis, ester hydrolysis, mono-oxidation, glucuronidation, and a combination of these reactions. From this study, 2-(4-((3r,5r,7r)-adamantan-1-yl)phenoxy)acetic acid (APA, M7), the metabolite produced via amide hydrolysis, was found to be a major circulating metabolite of LW6 in mice. The results of this study can be used to improve the pharmacokinetic profile by lowering the clearance and increasing the exposure relative to LW6. 相似文献
75.
This research study deals with the numerical solutions of linear and nonlinear time-fractional subdiffusion equations of distributed order. The main aim of our approach is based on the hybrid of block-pulse functions and shifted Legendre polynomials. We produce a novel and exact operational vector for the fractional Riemann–Liouville integral and use it via the Gauss–Legendre quadrature formula and collocation method. Consequently, we reduce the proposed equations to systems of equations. The convergence and error bounds for the new method are investigated. Six problems are tested to confirm the accuracy of the proposed approach. Comparisons between the obtained numerical results and other existing methods are provided. Numerical experiments illustrate the reliability, applicability, and efficiency of the proposed method. 相似文献
76.
Aastha Gupta Aditya Kaushik Manju Sharma 《Numerical Methods for Partial Differential Equations》2023,39(2):1220-1250
We propose a hybrid numerical scheme to discretize a class of singularly perturbed parabolic reaction–diffusion problems with robin-boundary conditions on an equidistributed grid. The hybrid difference scheme is developed by using a modified backward difference scheme in time, a combination of the cubic spline and exponential spline difference scheme in space. The proposed scheme uses a cubic spline difference scheme for the discretization of robin-boundary conditions. For the time discretization of the problem, we use the standard uniform mesh while a layer adapted equidistributed grid is generated for the spatial discretization. By equidistributing a curvature-based monitor function, the spatial adaptive grid is able to capture the presence of parabolic boundary layers without using any prior information about the solution. Parameter uniform error estimates are derived to illustrate an optimal convergence of first-order in time and second-order in space for the proposed discretization. The accuracy of the proposed scheme is confirmed by the numerical experiments that underpin the theoretical analysis. 相似文献
77.
The vacuum Rabi splitting and Kerr effect are investigated theoretically in a hybrid spin–magnon–photon system, where the nitrogen-vacancy center in diamond driven by two light fields is coupled to a spherical micromagnet embedded in a superconducting coplanar waveguide resonator. The results indicate that the phenomenon of the Mollow triplet and vacuum Rabi splitting can appear by controlling the spin–magnon coupling and magnon–photon coupling. It is shown that the probe absorption spectrum can be adjusted effectively via the pump frequency detuning. Moreover, it is demonstrated that the optical Kerr effect can be tuned by changing the Rabi frequency. This work may provide a possibility for the applications in quantum information processing and quantum sensing of magnetic signal. 相似文献
78.
79.
Muhammad Bilal Aman-ur- Rehman Shahzad Mahmood Muhammad Ahsan Shahzad Muhammad Sarfraz 《等离子体物理论文集》2023,63(1):e202200102
The dispersion properties and Landau damping rate of ion-acoustic waves (IAWs) with the hybrid Cairns-Tsallis distributed (CTD) electrons and Maxwellian ions are investigated using the plasma kinetic model based on Vlasov-Poisson's equations. For both super-extensive (q < 1) and sub-extensive (q > 1) plasmas, the dielectric response function, real frequency, and Landau damping rate of IAWs are derived. By taking the effect of θi, e (ion-to-electron temperature ratio) into account, it is found that with the increase of ion temperature, the real frequency and wave dispersion effects increase as well (for both super-extensive and sub-extensive cases). Exploring the properties of the Landau damping rate of IAWs with the simultaneous presence of non-thermal parameter α and non-extensive parameter q, a comparison of numerical and analytical results is presented. It is found that in different ranges of θe, i (electron-to-ion temperature ratio), on decreasing the values of the non-extensive parameter and increasing values of the non-thermal parameter, the weak damping rate is observed (vice versa) in super-extensive or super-thermal plasma, although the trend of the damping rate in sub-thermal plasma is similar (as in the case of super-thermal plasma) but is less weak. It is further revealed that the damping rate of IAWs in thermal plasmas (Maxwellian) is stronger than the damping rate of IAWs in the case of non-thermal plasmas (CTD). The current study is applicable to provide deep insight and further allow the exploration of electrostatic plasma modes in different space and laboratory plasma environments where the hybrid CTD plasma exists. 相似文献
80.
Jianpeng Li Dingshu Xiao Peichu Wang Hongyan Chen Minghua Deng Degang Zhu Jie Yu 《Particle & Particle Systems Characterization》2023,40(1):2200141
Transition metal compounds anchored on N-doped carbon (NC) show intrinsic activity and stability for oxygen reduction reaction (ORR). However, the interaction between the transition metal compounds and NC still needs to be strengthened for electron transfer at the compounds/carbon interface. Herein, Fe/Fe3C hybrid nanoparticles encapsulated into N-doped carbon (Fe@NC) are used as high-performance ORR catalysts. Benefiting from the strong interaction at Fe/Fe3C nanoparticles/NC interface, the electrons can transfer from Fe/Fe3C hybrid nanoparticles to NC, redistributing the electron density of active sites and promoting the ORR process. The as-synthesized Fe@NC exhibits outstanding ORR catalytic activity with an onset potential of 1.01 V and a half-wave potential of 0.92 V in alkaline media. It also shows prominent cycling stability and tolerance to methanol crossover, superior to Pt/C catalyst. The theoretical analysis reveals that the Fe nanoparticles have regulated the electron distributions at the heterojunction interface. The Gibbs free energy diagrams for ORR illustrate that the rate-determining step is the conversion of OH* to OH−. In situ Raman spectra give evidence of O-containing intermediates to prove the ORR process. 相似文献